Nanocrystals of a New Complex Perovskite Dielectric Ba2TmSbO6

M. M., Yusoff and Nair, V. M. and Rajan, Jose and Kumar, G. M. Anil and Wariar, P. R. S. (2012) Nanocrystals of a New Complex Perovskite Dielectric Ba2TmSbO6. Journal of Alloys and Compounds, 512 (1). pp. 207-211. ISSN 0925-8388 (print), 1873-4669 (online). (Published)

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Abstract

Nanocrystals of a new complex perovskites ceramic oxide, barium thulium antimony oxide – Ba2TmSbO6,were synthesized using a single step auto-ignition combustion process. The combustion product was single phase and composed of aggregates of nanocrystals of sizes in the range 20–50 nm. Ba2TmSbO6 crystallized in cubic perovskite structure with lattice parameter, a = 8.4101A˚ . The polycrystalline fluffy combustion product was sintered to high density (∼97%) at ∼1450 ◦C for 4 h. Resistivity of the sintered specimen was ∼5 M/cm. The Ba2TmSbO6 has dielectric constant (ε) and dielectric loss (tan ı) of 17 and ∼10−4 at 5 MHz; the new material would probably be developed as a low-loss dielectric material.

Item Type: Article
Additional Information: Indexed in Scopus, JCR 3 Citations. IF: 2.390
Uncontrolled Keywords: Nanocrystals; Dielectric; Barium rare-earth antimonates; Crystal structure; Rietveld analysis
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Faculty/Division: Faculty of Industrial Sciences And Technology
Depositing User: Prof. Dr. Mashitah Mohd Yusoff
Date Deposited: 18 Mar 2014 02:29
Last Modified: 16 Oct 2018 03:04
URI: http://umpir.ump.edu.my/id/eprint/4727
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