Ferrocene functionalized multi-walled carbon nanotubes as supercapacitor electrodes

Ali, Gomaa A. M. and Megiel, Elzbieta and Cieciórski, Piotr and Thalji, Mohammad R. and Romański, Jan and Algarni, H. and K. F., Chong (2020) Ferrocene functionalized multi-walled carbon nanotubes as supercapacitor electrodes. Journal of Molecular Liquids, 318 (114064). pp. 1-9. ISSN 0167-7322. (Published)

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Abstract

Modified multi-walled carbon nanotubes (MWCNTs) functionalized by a redox-active ferrocene (Fc-MWCNTs) were successfully synthesized to enhance the electrochemical performance of MWCNTs for supercapacitor application. The ferrocene moieties were attached to the surface of MWCNTs via a thiourea linker with anions-interacting capability. The Fc-MWCNTs were characterized using XPS, FTIR, SEM, TGA, DTG, and XRF methods. The electrochemical performance details were investigated using cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy. The Fc-MWCNTs electrode showed excellent capacity retention (90.8% over 5000 cycles) and a specific capacitance of 50 F g−1 at 0.25 A g−1 that is several times higher as compared to the pristine MWCNTs. The fabricated Fc-MWCNTs is proposed to be a suitable and promising candidate for energy storage material. dec

Item Type: Article
Uncontrolled Keywords: Ferrocene; Functionalization; Multi-walled carbon nanotubes; Supercapacitor electrodes
Subjects: T Technology > TA Engineering (General). Civil engineering (General)
Faculty/Division: Faculty of Industrial Sciences And Technology
Institute of Postgraduate Studies
Depositing User: Noorul Farina Arifin
Date Deposited: 01 Sep 2020 07:57
Last Modified: 01 Sep 2020 07:57
URI: http://umpir.ump.edu.my/id/eprint/29155
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