Sarkar, Shaheen M. and Lutfor, M. R. and M. M., Yusoff (2015) Highly Active Thiol-functionalized SBA-15 Supported Palladium catalyst for Sonogashira and Suzuki-Miyaura Cross-coupling Reactions. RSC Advances, 5. pp. 1295-1300. ISSN 2046-2069. (Published)
Full text not available from this repository. (Request a copy)Abstract
Highly ordered mesoporous silica SBA-15 with pendent 3-mercaptopropyl groups has been prepared by condensation of surface silanols and (3-mercaptopropyl)trimethoxysilane. Treatment of the mercaptopropylated SBA-15 with (CH3CN)2PdCl2 gave a heterogeneous Pd-catalyst. The immobilized Pd-catalyst served as an efficient heterogeneous catalyst for Sonogashira and SuzukiâÂÂMiyaura cross coupling reactions of aryl halides. Furthermore, the SBA-15 supported Pd-catalyst was recovered by a simple filtration from the reaction mixture and reused five times without significant loss of its catalytic activity.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > Q Science (General) |
| Faculty/Division: | Faculty of Industrial Sciences And Technology |
| Depositing User: | Dr. Md Shaheen Sarkar |
| Date Deposited: | 08 Jan 2015 07:20 |
| Last Modified: | 14 Feb 2018 04:01 |
| URI: | http://umpir.ump.edu.my/id/eprint/8101 |
| Download Statistic: | View Download Statistics |
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