Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions

Sarkar, Shaheen M. and Lutfor, M. R. and M. M., Yusoff (2015) Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions. RSC Advances, 5 (25). pp. 19630-19637. ISSN 2046-2069. (Published)

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Abstract

An MCM-48 supported 2-pyridinylmethanimine Pd-catalyst was found to be a highly efficient catalyst in the Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under aqueous reaction conditions. The catalyst efficiently promoted these coupling reactions with ppm levels of palladium to afford the corresponding coupling products in up to 98% yield. The supported Pdcatalyst was readily recovered and reused several times without significant loss of its catalytic activity.

Item Type: Article
Subjects: Q Science > QD Chemistry
Faculty/Division: Faculty of Industrial Sciences And Technology
Depositing User: Dr. Md Shaheen Sarkar
Date Deposited: 11 Apr 2016 08:02
Last Modified: 14 Feb 2018 04:08
URI: http://umpir.ump.edu.my/id/eprint/12769
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