Mandal, Bablu Hira and Sarkar, Shaheen M. and Lutfor, M. R. and Mohd Hasbi, Ab. Rahim (2016) Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions. In: Proceedings of The National Conference for Postgraduate Research (NCON-PGR 2016) , 24-25 September 2016 , Universiti Malaysia Pahang (UMP), Pekan, Pahang. pp. 663-675..
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Abstract
A highly active kenaf cellulose supported poly(amidoxime) palladium catalyst was sythesized and the catalyst (65 mol ppm to 6.5 mol ppm) was found to promote efficiently allylic arylation of allylic ester with sodium tetraarylborates and arylboronic acids in ethanol at 60 °C temperature. Oustanding yields of the corresponding products as well as significant reusability of the catalyst were obtained. The total turnover number(TON) and frequency(TOF) were 144615 and 9641 h–1 respectively.
| Item Type: | Conference or Workshop Item (Lecture) |
|---|---|
| Uncontrolled Keywords: | kenaf, cellulose, poly(amidoxime)Pd-complex, allylic arylatio |
| Subjects: | T Technology > TA Engineering (General). Civil engineering (General) |
| Faculty/Division: | Faculty of Industrial Sciences And Technology Institute of Postgraduate Studies |
| Depositing User: | Rosfadilla Mohamad Zainun |
| Date Deposited: | 16 Dec 2016 06:58 |
| Last Modified: | 10 Sep 2019 02:36 |
| URI: | http://umpir.ump.edu.my/id/eprint/15778 |
| Download Statistic: | View Download Statistics |
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