Bahari, M. B. and Jun, Lau N. and Nor Shafiqah, Mohd Nasir and Fayaz, Fahim and Vo, Dai-Viet N. (2018) Ethylene glycol dry reforming on Ni/Al2O3 catalyst for syngas generation. In: IOP Conference Series: Materials Science and Engineering, 3rd International Conference on Energy Materials and Applications , 9-11 May 2018 , University of Salamanca, Salamanca. pp. 1-6., 446 (012013). ISSN 1757-8981 (Print), 1757-899X (Online)
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Abstract
It is the first time ethylene glycol dry reforming (EGDR) reaction was carried out for syngas production on 10%Ni/Al2O3 catalyst in a tubular fixed-bed reactor at atmospheric condition. Wet-impregnation method was employed for the synthesis of 10%Ni/Al2O3 catalyst. The results of X-ray diffraction measurement revealed the presence of γ-Al2O3, NiO, NiAl2O4, Ni0 and graphitic carbon phases on the surface of spent 10%Ni/Al2O3 catalyst. H2 temperature-programmed reduction indicates that NiO and NiAl2O4 phases were totally reduced to metallic nickel phase at reduction temperature above 970 K. EGDR activity appeared to be steady with time-on-stream beyond 5-7 h. Catalytic activity was considerably improved with increasing feed ratio of CO2:C2H6O2 from 1:1 to 2.5:1.
| Item Type: | Conference or Workshop Item (Lecture) |
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| Uncontrolled Keywords: | Ethylene glycol dry reforming; Ni/Al2O3; Syngas |
| Subjects: | T Technology > TP Chemical technology |
| Faculty/Division: | Centre of Excellence: Centre of Excellence for Advanced Research in Fluid Flow Faculty of Chemical & Natural Resources Engineering Institute of Postgraduate Studies |
| Depositing User: | Dr. Vo Nguyen Dai Viet |
| Date Deposited: | 08 Feb 2019 04:08 |
| Last Modified: | 03 Oct 2019 08:04 |
| URI: | http://umpir.ump.edu.my/id/eprint/21193 |
| Download Statistic: | View Download Statistics |
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