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Isomerization of linear c5-c7 over pt loaded on protonated fibrous silica@y zeolite (Pt/Hsi@Y)

S., Triwahyono and A. A., Jalil and N. S., Jamari and M. L., Firmansyah and N. A., Fatah and S. M., Izan and S. F., Jamian and Herma Dina, Setiabudi (2018) Isomerization of linear c5-c7 over pt loaded on protonated fibrous silica@y zeolite (Pt/Hsi@Y). In: 4th International Conference Of Chemical Engineering And Industrial Biotechnology (ICCEIB 2018), 1-2 August 2018 , Seri Pacific Hotel, Kuala Lumpur. pp. 98-100..

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Abstract

Silica-based fibrous material has been extensively studied by researchers after the discovery of fibrous silica nanosphere (KCC-1) by Polshettiwar et al., 2010. The KCC-1 was first prepared using the microwave-assisted hydrothermal technique exhibited excellent properties, including a high surface area, a fibrous surface morphology, good thermal and hydrothermal stabilities and mechanical stability. Moon, et al., (2012) reported that the mesoporous silica with fibrous morphology has high surface area compared with a typical hexagonal or cubic pore structure which suitable for good catalytic support. Previous study has many discovered related to the acid-catalyzed for isomerization reaction. They discovered that the isomerization supports must have appropriated acidity for the good catalytic activity. However, the KCC-1 which fully composed with silica does not provided an adequate acid sites to promote acid-catalyzed isomerization reaction [1,2]. In the present work, newly combined zeolite-based with fibrous silica was prepared via self-assembly process in the microemulsion system. This new catalyst has a potential to overcome inadequate acidity provided by KCC-1. Therefore, implementation of combined silica based material with zeolite enhanced the acidity of the catalyst to overcome the inadequate acidity provided by solely silica of KCC-1. The high acidity will enhanced the isomerization reaction towards producing high octane number gasoline [3].

Item Type: Conference or Workshop Item (Lecture)
Uncontrolled Keywords: Pt/HSi@Y; Fibrous Silica; Y zeolite; acidic sites; C5-C7 isomerization
Subjects: T Technology > TP Chemical technology
Faculty/Division: Faculty of Chemical & Natural Resources Engineering
Depositing User: Pn. Hazlinda Abd Rahman
Date Deposited: 08 Jan 2019 04:20
Last Modified: 08 Jan 2019 04:20
URI: http://umpir.ump.edu.my/id/eprint/23664
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