Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes

Norfatihah, Mazuki and Nur Muhitul Jalilah, Rasali and Saadiah, M. A. and Ahmad Salihin, Samsudin (2018) Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes. In: AIP Conference Proceedings: 4th International Conference on Green Design and Manufacture 2018, IConGDM 2018 , 29-30 April 2018 , Ho Chi Minh, Vietnam. pp. 1-7., 2030 (020221). ISSN 0094-243X ISBN 978-0-7354-1752-6

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Abstract

In this present work, solid biopolymer electrolytes (SBEs) system consists of the blended polymer namely carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) doped ammonium chloride (NH4Cl) at different composition from 0 to 10 wt. % were successfully prepared by using casting technique. The electrical conductivity of solid biopolymer electrolytes (SBEs) system was investigated by using Electrical Impedance Spectroscopy (EIS). Electrical study shows the highest ionic conductivity in room temperature (303 K) was achieved at 8.86 × 10−5 Scm−1 for sample containing 6 wt. % of NH4Cl. The present system shown unexpected drop after different amount of NH4Cl (1-5 wt. %) were added into the CMC/PVA and its might attributed to the factor of composition of dopant. All SBEs systems were found to be obeys Arrhenius behaviour where the plots show close to unity (R2∼1) and thermally activated.

Item Type:	Conference or Workshop Item (Lecture)
Additional Information:	Indexed by Scopus N. F., Mazuki = Norfatihah Mazuki
Uncontrolled Keywords:	Ionic conductivity; Electrical conductivity; Electrolytes; Polymers; Electrical impedance spectroscopy; Biopolymers
Subjects:	Q Science > Q Science (General) Q Science > QC Physics Q Science > QD Chemistry
Faculty/Division:	Faculty of Industrial Sciences And Technology
Depositing User:	Dr. Ahmad Salihin Samsudin
Date Deposited:	28 Jan 2019 08:08
Last Modified:	04 Dec 2023 02:47
URI:	http://umpir.ump.edu.my/id/eprint/23991
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