Ethylene glycol dry reforming for syngas generation on Ce‑promoted Co/Al2O3 catalysts

Lau, N. Jun and Mahadi, Bahari and Pham, T. T. Phuong and Nguyen, Huu Huy Phuc and Chanatip, Samart and Bawadi, Abdullah and Setiabudi, H. D. and Vo, Dai-Viet N. (2018) Ethylene glycol dry reforming for syngas generation on Ce‑promoted Co/Al2O3 catalysts. Applied Petrochemical Research, 8 (4). pp. 253-261. ISSN 2190-5533. (Published)

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Abstract

Ethylene glycol dry reforming (EGDR) was investigated for the first time on 10% Co/Al2O3 and 3% Ce–10% Co/Al2O3 catalysts at stoichiometric feed composition under atmospheric pressure and 923–998 K for syngas production. Catalysts were characterized using BET, H2-TPR, XRD and Raman spectroscopy measurements. The addition of Ce promoter eased the reduction of Co3O4 with lower reduction temperature and enhanced metal dispersion. Ce promotion also improved EGDR performance by increasing reactant conversions, syngas yields and reducing undesirable methane formation. The conversion of ethylene glycol and H2 yield reached up to 71.7% and 69.3%, respectively.

Item Type: Article
Uncontrolled Keywords: Ethylene glycol; dry reforming; co-based catalysts; syngas; ce promoter; hydrogen
Subjects: T Technology > TA Engineering (General). Civil engineering (General)
Faculty/Division: Faculty of Chemical & Natural Resources Engineering
Institute of Postgraduate Studies
Depositing User: Miss. Ratna Wilis Haryati Mustapa
Date Deposited: 23 Jan 2020 06:43
Last Modified: 29 Jan 2020 01:16
URI: http://umpir.ump.edu.my/id/eprint/27560
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