Facile synthesis of fibrous Faujasite Y supported Ni (Ni/FFY) catalyst for hydrogen production via glycerol dry reforming

Nornasuha, Abdullah and Nurul Aini, Razali and Herma Dina, Setiabudi and Asmida, Ideris and A. R., Mohamed and A. A., Jalil (2023) Facile synthesis of fibrous Faujasite Y supported Ni (Ni/FFY) catalyst for hydrogen production via glycerol dry reforming. Materials Today: Proceedings. pp. 1-7. ISSN 2214-7853. (In Press / Online First) (In Press / Online First)

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Abstract

In this study, the dendritic structure of Ni-supported Fibrous Faujasite Y (Ni/FFY) catalyst was successfully synthesized by employing a hydrothermal-assisted microemulsion system and subsequently tested in glycerol dry reforming to produce syngas. FFY possesses high porosity due to the formation of radial wrinkle fibre observed from TEM analysis. This provides a huge amount of interparticle pores that facilitate the absorption of the molecules within the material under a minimum hindrance, hence boosting the interior surface accessibility of Ni/FFY. This exclusive morphology contributed to the enhancement in the amount of accessible Ni active sites, resulting in the good activity of Ni/FFY (C3H8O3 conversion = 56.28 %, CO yield = 70.14 %, and H2 yield = 49.80 %). The extraordinary physicochemical properties of Ni/FFY and outstanding catalytic performance in glycerol dry reforming proved its capability as a sustainable catalyst in transforming waste byproduct (glycerol) and greenhouse gas (CO2) to clean energy (H2). This finding presents a pioneering fibrous zeolite catalyst for hydrogen generation in glycerol reforming.

Item Type:	Article
Uncontrolled Keywords:	Zeolite Y; Dendritic morphology; Interparticle porosity; Ni catalyst; Hydrogen; Dry reforming
Subjects:	T Technology > TP Chemical technology
Faculty/Division:	Centre of Excellence: Centre of Excellence for Advanced Research in Fluid Flow Institute of Postgraduate Studies Faculty of Chemical and Process Engineering Technology
Depositing User:	Mrs Norsaini Abdul Samat
Date Deposited:	28 Feb 2024 06:55
Last Modified:	28 Feb 2024 06:55
URI:	http://umpir.ump.edu.my/id/eprint/40532
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