Improvement in stability and thermophysical properties of CNC-MXene nanolubricant for Tribology application

Mohd Kamal, Kamarulzaman and Sakinah, Hisham and Kadirgama, Kumaran and Devarajan, Ramasamy and Samykano, Mahendran and Said, Zafar and Pandey, A. K. (2023) Improvement in stability and thermophysical properties of CNC-MXene nanolubricant for Tribology application. Journal of Molecular Liquids, 381 (121695). pp. 1-16. ISSN 0167-7322. (Published)

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Abstract

The primary objective of the present work is to carry out an experimental study into the stability and thermophysical characteristics of cellulose nanocrystal, MXene, and hybrid cellulose nanocrystal-MXene added to engine oil as a lubricant for piston ring-cylinder liner application. There have been experiments with stability techniques like sedimentation observation, UV–visible spectroscopy, and zeta potential. Thermophysical characteristics have been measured using the viscosity index, dynamic viscosity, and thermal conductivity at various concentrations (ranging from 0.01 % to 0.05 %) and temperatures (from 40 °C to 100 °C). Even without any surfactants, the cellulose nanocrystal-MXene nanolubricants showed good dispersion during the first seven days. The results of the ultraviolet–visible spectrophotometer indicate that cellulose nanocrystal nanolubricants exhibit an absorbance ratio that is most similar to one. It can be shown that the zeta potential increases with a concentration in the distribution of cellulose nanocrystal, MXene, and cellulose nanocrystal-MXene nanoparticles. According to the viscosity index results, all nanolubricants reduce the lubricity oil's viscosity by 16.77 % to 20.33 %, with cellulose nanocrystal-MXene showing the greatest improvement at 0.05 %. At solid concentrations of 0.01 % cellulose nanocrystal and 0.05 % cellulose nanocrystal-MXene with temperatures of 40 °C and 90 °C, the dynamic viscosity was enhanced by 0.92 % and 130.87 %, respectively. The solid concentration of 0.05 % cellulose nanocrystal-MXene was determined to have the greatest effect on the thermal conductivity ratio of the chosen nanolubricant at 90 °C. Overall, at an average concentration of 0.05 %, the thermophysical properties' performance was increased by the addition of cellulose nanocrystal-MXene nanoparticle. The study's findings may be useful for applications involving heat transmission, particularly tribological ones.

Item Type: Article
Additional Information: Indexed by Scopus
Uncontrolled Keywords: Cellulose nanocrystal; Hybrid nanolubricant; MXene; Thermal conductivity; Viscosity
Subjects: T Technology > TJ Mechanical engineering and machinery
Faculty/Division: Faculty of Mechanical and Automotive Engineering Technology
Institute of Postgraduate Studies
Centre of Excellence: Automotive Engineering Centre
Centre of Excellence: Automotive Engineering Centre

Centre for Research in Advanced Fluid & Processes (Fluid Centre)
Depositing User: AP. Ir. Dr Mahendran Samykano
Date Deposited: 26 Apr 2024 09:00
Last Modified: 26 Apr 2024 09:00
URI: http://umpir.ump.edu.my/id/eprint/41066
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