M. M., Yusoff and Talaty, Erach R (1996) Ring-expansion of an Aziridinone to a Hexahydrotriazine Through the Agency of a Novel Rearrangement. Tetrahedron Letters, 37 (48). pp. 8695-8698. ISSN 0040-4039. (Published)
Full text not available from this repository. (Request a copy)Abstract
Reaction of 1,3-di-t,'rt-bu~.laziridinonc (la) and similar aziridinones with thiosemicarbazide affords, as one of the products, a compound devoid of sulfur, vie., a substituted N- aminoimidazolidinone (3a) by selective cleavage of the acyl-nitrogcn bond. Compound 3a undergoes a novel, acid-catalyzed rearrangement to a 3-imino-hexahydro-1,2,4-tri~in-6-one (7a), which can also be obtained ~' treatment of la with hydrazinc followed by BrCN. involving again selective cleavage of the acyl-nitrogen bond.
| Item Type: | Article |
|---|---|
| Additional Information: | Please click to official URL. Cited by 13. |
| Uncontrolled Keywords: | Aziridinone; Hexahydrotriazine |
| Subjects: | Q Science > Q Science (General) |
| Faculty/Division: | Faculty of Industrial Sciences And Technology |
| Depositing User: | Prof. Dr. Mashitah Mohd Yusoff |
| Date Deposited: | 28 Jan 2014 07:02 |
| Last Modified: | 22 Jan 2018 01:36 |
| URI: | http://umpir.ump.edu.my/id/eprint/4788 |
| Download Statistic: | View Download Statistics |
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