Oxygen Vacancy-rich Mesoporous Silica KCC-1 for CO2 Methanation

M. Y. S., Hamid and M. L., Firmansyah and S., Triwahyono and A. A., Jalil and R. R., Mukti and E., Febriyanti and V., Suendo and Setiabudi, H. D. and M., Mohamed and W., Nabgan (2017) Oxygen Vacancy-rich Mesoporous Silica KCC-1 for CO2 Methanation. Applied Catalysis A: General, 532. pp. 86-94. ISSN 0926-860X. (Published)

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Abstract

Mesoporous silica KCC-1 was successfully synthesized by microemulsion system coupled with microwave-assisted hydrothermal method. Mesoporous silica KCC-1 exhibited spherical morphology surrounded with dendritic fiber with the particle size of 200–400 nm and BET surface area of 773 m2/g. Mesoporous silica KCC-1 has significantly higher number of basicity and oxygen vacancy than those of MCM-41 and SiO2 which directly correlated with the catalytic performance of the catalyst. The activity of mesoporous silica KCC-1 in CO2 methanation is five-fold higher than MCM-41 with the yield of CH4 reached 38.9% at 723 K.

Item Type: Article
Uncontrolled Keywords: Mesoporous silica KCC-1; Microemulsion system; CO2 methanation; Oxygen vacancy; Basicity
Subjects: T Technology > TP Chemical technology
Faculty/Division: Faculty of Chemical & Natural Resources Engineering
Depositing User: Mrs. Neng Sury Sulaiman
Date Deposited: 16 Jun 2017 07:15
Last Modified: 16 Jun 2017 07:15
URI: http://umpir.ump.edu.my/id/eprint/16548
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