Mandal, Bablu Hira and Lutfor, M. R. and M. M., Yusoff and K. F., Chong and Sarkar, Shaheen M. (2017) Bio-waste Corn-cob Cellulose Supported Poly(hydroxamic acid) Copper Complex for Huisgen Reaction: Waste to Wealth Approach. Carbohydrate Polymers, 156. pp. 175-181. ISSN 0144-8617. (Published)
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Abstract
Corn-cob cellulose supported poly(hydroxamic acid) Cu(II) complex was prepared by the surface modification of waste corn-cob cellulose through graft copolymerization and subsequent hydroximation. The complex was characterized by IR, UV, FESEM, TEM, XPS, EDX and ICP-AES analyses. The complex has been found to be an efficient catalyst for 1,3-dipolar Huisgen cycloaddition (CuAAC) of aryl/alkyl azides with a variety of alkynes as well as one-pot three-components reaction in the presence of sodium ascorbate to give the corresponding cycloaddition products in up to 96% yield and high turn over number (TON 18,600) and turn over frequency (TOF 930 h−1) were achieved. The complex was easy to recover from the reaction mixture and reused six times without significant loss of its catalytic activity.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Corn-cob; Cellulose; Copper; Poly(hydroxamic acid); Huisgen reaction |
| Subjects: | Q Science > Q Science (General) |
| Faculty/Division: | Faculty of Industrial Sciences And Technology Institute of Postgraduate Studies |
| Depositing User: | Mrs. Neng Sury Sulaiman |
| Date Deposited: | 15 Feb 2017 03:56 |
| Last Modified: | 10 Sep 2019 02:27 |
| URI: | http://umpir.ump.edu.my/id/eprint/16576 |
| Download Statistic: | View Download Statistics |
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