Rassem, Hesham H. A. and Nour, A. H. (2016) Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide. Australian Journal of Basic and Applied Sciences, 10 (1). pp. 513-516. ISSN 1991-8178. (Published)
|
PDF
fkksa-2016-nhabdurahman-Synthesis, Spectra.pdf Download (195kB) | Preview |
Abstract
A Schiff base, (E)-4-Hydroxy-N -(2-methoxybenzylidene) benzohydrazide, (E4HB) had been synthesized in good yield by the acid-catalyzed condensation methoxybenzaldehyde and 4-hydroxybenzhydrazide in synthesized compound was elucidated by elemental analysis (CHN), FTIR, 13C-NMR and single crystal X-ray diffraction. E4HB crystallized in the crystal system with space group Z = 8, V = 2656.74(10) Å3 14.3951(3) Å, b = 8.7449(2) Å, c =21.1047(4) Å . The crystal structure of the compound is stabilized by intermolecular N1—H1N1….O2, O1 C13—H13A…O1 hydrogen bonds. A π—π interaction with centroid of 3.628 (6) A also occurs (Cg1 = C9— C14, -x, -y, -z).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | 2-methoxybenzaldehyde; 4-hydroxybenzoylhydrazine; Methanol; Hydrochloric acid |
| Subjects: | T Technology > TP Chemical technology |
| Faculty/Division: | Faculty of Chemical & Natural Resources Engineering |
| Depositing User: | Noorul Farina Arifin |
| Date Deposited: | 24 Feb 2017 05:09 |
| Last Modified: | 24 Jan 2018 04:09 |
| URI: | http://umpir.ump.edu.my/id/eprint/16838 |
| Download Statistic: | View Download Statistics |
Actions (login required)
 |
View Item |