Tailoring the Properties and Catalytic Activities of Ni/SBA-15 via Different TEOS/P123 Mass Ratios for CO2 Reforming of CH4

Syahida Nasuha, Bukhari and Chin, S. Y. and Setiabudi, H. D. and Vo, Dai-Viet N. (2017) Tailoring the Properties and Catalytic Activities of Ni/SBA-15 via Different TEOS/P123 Mass Ratios for CO2 Reforming of CH4. Journal of Environmental Chemical Engineering, 5 (4). pp. 3122-3128. ISSN 2213-3437. (Published)

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DOI/Official URL: https://doi.org/10.1016/j.jece.2017.06.012

Abstract

The influences of tetraethylorthosilicate/ triblockcopolymer (TEOS/P123) mass ratios on the properties and catalytic activity of Ni/SBA-15 towards CO2 reforming of CH4 were studied. A series of samples with different mass ratios of TEOS/P123 (1.5, 2.21 and 3.0) were prepared and characterized by XRD, BET, SEM, TEM, FTIR and UV–vis DRS. The characterization results clearly indicated that TEOS/P123 mass ratio of 2.21 was the optimal synthesis ratio of Ni/SBA-15 which produces the well-ordered hexagonal mesoporous structure with the highest Ni-support interaction. The catalytically favorable textural properties of Ni/SBA-15(R2.21) enhanced the dispersion of metal particles, improved the catalyst activity, increased the catalyst stability and reduced the carbon deposition. The conversion of CH4 and CO2 over Ni/SBA-15(R2.21) were about 89% and 88%, respectively and H2/CO ratio of 1.02. This study provides new perspectives on the Ni-based catalyst, particularly on the influence of TEOS/P123 mass ratio on the properties and catalytic activity of Ni/SBA-15 towards CO2 reforming of CH4.

Item Type:	Article
Uncontrolled Keywords:	Ni/SBA-15; CH4 dry reforming; TEOS/P123; CO2 conversion; Metal dispersion
Subjects:	T Technology > TP Chemical technology
Faculty/Division:	Faculty of Chemical & Natural Resources Engineering
Depositing User:	Mrs. Neng Sury Sulaiman
Date Deposited:	09 Aug 2017 04:49
Last Modified:	18 Oct 2018 06:55
URI:	http://umpir.ump.edu.my/id/eprint/18073
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