The preparation of liquefied bio-stalk carbon nanofibers and their application in supercapacitors

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Abstract

Carbon nanofibers (CNFs) have been widely used in electrochemical energy storage devices because of their excellent conductivity, extremely large surface area and structural stability. Herein, we obtained a viscous, liquefied bio-stalk carbon via the simple chemical treatment of biomass, and mixed it with polyacrylonitrile to prepare a spinning solution. Subsequent electrospinning and high temperature activation resulted in the successful preparation of liquefied lignin-based activated carbon nanofibers. The as-prepared liquefied bio-stalk carbon nanofibers exhibited an outstanding electrochemical performance (specific capacitance of 273 F g−1 at 0.5 A g−1 current density), and a capacitance retention of 210 F g−1 even under a large current density of 10 A g−1. Besides its high specific capacitance and outstanding rate capability, the symmetrical supercapacitor cell based on the liquefied carbon-based nanofiber electrodes also exhibited an excellent cycling performance with 92.76% capacitance retention after 5000 charge–discharge cycles. This study provides a new strategy for the future development of supercapacitor electrode materials and enhances the development of biomass energy.

Item Type: Article
Uncontrolled Keywords: carbon nanofibers; energy storage devices; supercapacitors
Subjects: T Technology > TP Chemical technology
Faculty/Division: Faculty of Engineering Technology
Depositing User: Noorul Farina Arifin
Date Deposited: 06 Aug 2019 06:40
Last Modified: 06 Aug 2019 06:40
URI: http://umpir.ump.edu.my/id/eprint/25600
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