PI/NCC-based carbon molecular sieve membranes for hydrogen purification : effect of aging times

Norazlianie, Sazali and W. N. W., Salleh and Siregar, J. P. and M. H. D., Othman and J., Jaafar and T., Gunawan (2020) PI/NCC-based carbon molecular sieve membranes for hydrogen purification : effect of aging times. In: IOP Conference Series: Materials Science and Engineering; Energy Security and Chemical Engineering Congress (ESChE) 2019 , 17-19 July 2019 , Kuala Lumpur, Malaysia. pp. 1-7., 736 (022003). ISSN 1757-8981 (Print), 1757-899X (Online)

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Abstract

In this study, the effect of stabilization temperature on the performance of tubular carbon Upgrade the gas separation performance of the resultant carbon molecular sieve (CMS) membrane, a synthesized nanocrystalline cellulose (NCC) utilizing tissue paper as an added substance was included into the simpleton arrangement at pyrolysis temperatures of 800°C. This paper shows the inference of CMSs from BTDA-TDI/MDI polyimide (PI) arranged by means of a dip-coating strategy on an inorganic cylindrical help surface, trailed by a heat treatment (adjustment and carbonization) under Ar gas stream. Extraordinary consideration was given to the physicochemical attributes of the subsequent PI/NCC-based CMS and its comparing gas permeation properties. Pure gas permeation tests were performed utilizing H2, and N2 at room temperature. The gas permeation information showed that the CMS displayed an amazing performance contrasted with the polymeric membrane. Upgrade in the two gas permeance and selectivity were watched arranged with fresh CMS membrane, with H2N2 selectivity of 434.68±1.39, regarding the neat CMS. By controlling different aging times (fresh, 1 day, multi week, and 3 months), CMSs with various structures and properties were gotten.

Item Type:	Conference or Workshop Item (Lecture)
Uncontrolled Keywords:	Carbon molecular sieve (CMS); Aging times; P84 co-polyimide; Nanocrystalline cellulose (NCC); Hydrogen purification
Subjects:	Q Science > Q Science (General) T Technology > TP Chemical technology
Faculty/Division:	Centre of Excellence: Centre of Excellence for Advanced Research in Fluid Flow Faculty of Mechanical Engineering
Depositing User:	Dr. Norazlianie Sazali
Date Deposited:	11 Mar 2020 02:37
Last Modified:	11 Mar 2020 02:37
URI:	http://umpir.ump.edu.my/id/eprint/28081
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