Study of Ionic Liquids (AIL and PIL) Viscosity and its Functional Groups under Heat Treatment on Cutting Tool Surface Using Fourier- Transform Infrared Spectroscopy (FTIR)

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Abstract

This study was conducted to investigate the efficiency of Minimum Quantity Lubrication (MQL) technique by using Modified Jatropha Oil (MJO) bio-based lubricant with the presence of 10% Ammonium Ionic Liquid (MJO+AIL10%) and 1% Phosphonium Ionic Liquid (MJO+PIL1%) additives respectively at various temperature of 200 C, 300 C and 400 C heat treatment to determine the ability to exhibit corrosion and wear throughout the process. Fourier-Transform Infrared Spectroscopy (FTIR) analysis revealed prominent peaks of functional groups in these bio-lubricants; esters (C-O) and (C=O), alkanes (C-H), hydroxide (O-H), and nitrile groups deposited on the cutting tool surface. Initially, nitrile group is detected on cutting tool surface without lubricants at 2200 cm−1 to 2300 cm−1 absorption band reduced to lower intensity and most likely concealed by MJO+AIL10% compared to MJO+PIL1% where the nitrile group remains reflected in FTIR spectrum. In this work, it is proved that MJO+AIL10% has higher viscosity as compared to MJO+PIL1%. in the context of functional groups and supported the previous study on MJO+AIL10% as corrosion inhibitor.

Item Type: Article
Uncontrolled Keywords: bio-lubricant, ionic liquids, FTIR analysis, viscosity, nitriles compound
Subjects: Q Science > QD Chemistry
T Technology > TA Engineering (General). Civil engineering (General)
T Technology > TP Chemical technology
Faculty/Division: Faculty of Manufacturing and Mechatronic Engineering Technology
Depositing User: Dr. Amiril Sahab Abdul Sani
Date Deposited: 17 May 2021 08:10
Last Modified: 17 May 2021 08:10
URI: http://umpir.ump.edu.my/id/eprint/30939
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