Tran, Ngoc Thang and Pham, Thong Le Minh and Nguyen, Trinh Duy and Cuong, Nguyen Van and Siang, Tan Ji and Phuong, Pham T.T. and A.A., Jalil and Truong, Quang Duc and Sumaiya, Zainal Abidin and Hagos, Ftwi Y. and Sonil, Nanda and N. Vo, Dai-Viet (2021) Improvements in hydrogen production from methane dry reforming on filament-shaped mesoporous alumina-supported cobalt nanocatalyst. International Journal of Hydrogen Energy, 46 (48). pp. 24781-24790. ISSN 0360-3199. (Published)
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Abstract
The mesoporous gamma-alumina (g-Al2O3) synthesized via evaporation-induced self-assembly method (EISA) using inorganic salt, Al(NO3)3$9H2O precursor and water-ethanol solvent mixture was implemented as a support for Co catalyst in methane dry reforming at 973e1073 K under 1 atm. The g-Al2O3 support possessed filament-shaped morphology with surface area of 173.4 m2 g1 and cobalt nanoparticles were successfully dispersed on support with small crystallite size of 7.8 nm. The stability of 10%Co/Al2O3 was evident for CH4 and CO2 conversions at 1023 and 1073 K. CH4 conversion could reach to 76.2% while 81.6% was observed for CO2 conversion at 1073 K. Although graphitic and amorphous carbons were unavoidably formed on used catalyst, 10%Co/Al2O3 exhibited an outstanding performance comparable to noble metals with the desired ratio of H2/CO for downstream Fischer-Tropsch process.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Mesoporous alumina; Cobalt; catalyst; Hydrogen Syngas Methane dry reforming |
| Subjects: | T Technology > T Technology (General) T Technology > TP Chemical technology |
| Faculty/Division: | Faculty of Chemical & Natural Resources Engineering Institute of Postgraduate Studies Centre of Excellence: Automotive Engineering Centre Centre of Excellence: Automotive Engineering Centre |
| Depositing User: | Miss. Ratna Wilis Haryati Mustapa |
| Date Deposited: | 15 Jul 2021 07:49 |
| Last Modified: | 15 Jul 2021 07:53 |
| URI: | http://umpir.ump.edu.my/id/eprint/31605 |
| Download Statistic: | View Download Statistics |
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