Wu, Zong-Han and Shih, Jeng-Ywan and Li Ying-, Jeng James and Tsai, Yi-De and Hung, Tai-Feng and Karuppiah, Chelladurai and Jose, Rajan and Yang, Chun-Chen (2022) MoO3 nanoparticle coatings on high-voltage 5 V LiNi0.5 Mn1.5 O4 cathode materials for improving lithium-ion battery performance. Nanomaterials, 12 (3). pp. 1-18. ISSN 2079-4991. (Published)
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MoO3 nanoparticle coatings on high-voltage 5 V LiNi0.5 Mn1.5 O4 cathode materials for improving lithium-ion battery performance.pdf Available under License Creative Commons Attribution. Download (2MB) | Preview |
Abstract
To reduce surface contamination and increase battery life, MoO3 nanoparticles were coated with a high-voltage (5 V) LiNi0.5 Mn1.5 O4 cathode material by in-situ method during the high-temperature annealing process. To avoid charging by more than 5 V, we also developed a system based on anode-limited full-cell with a negative/positive electrode (N/P) ratio of 0.9. The pristine LiNi0.5 Mn1.5 O4 was initially prepared by high-energy ball-mill with a solid-state reaction, followed by a precipitation reaction with a molybdenum precursor for the MoO3 coating. The typical structural and electrochemical behaviors of the materials were clearly investigated and reported. The results revealed that a sample of 2 wt.% MoO3-coated LiNi0.5 Mn1.5 O4 electrode exhibited an optimal electrochemical activity, indicating that the MoO3 nanoparticle coating layers considerably enhanced the high-rate charge–discharge profiles and cycle life performance of LiNi0.5 Mn1.5 O4 with a negligible capacity decay. The 2 wt.% MoO3-coated LiNi0.5 Mn1.5 O4 electrode could achieve high specific discharge capacities of 131 and 124 mAh g−1 at the rates of 1 and 10 C, respectively. In particular, the 2 wt.% MoO3-coated LiNi0.5 Mn1.5 O4 electrode retained its specific capacity (87 mAh g−1) of 80.1% after 500 cycles at a rate of 10 C. The Li4 Ti5 O12 /LiNi0.5 Mn1.5 O4 full cell based on the electrochemical-cell (EL-cell) configuration was successfully assembled and tested, exhibiting excellent cycling retention of 93.4% at a 1 C rate for 100 cycles. The results suggest that the MoO3 nano-coating layer could effectively reduce side reactions at the interface of the LiNi0.5 Mn1.5 O4 cathode and the electrolyte, thus improving the electrochemical performance of the battery system.
| Item Type: | Article |
|---|---|
| Additional Information: | Indexed by Scopus |
| Uncontrolled Keywords: | 5 V cathode materials; High-energy ball-mill method; High-rate performance; MoO3-coated; Spinel-type LiNi0.5 Mn1.5 O4 |
| Subjects: | H Social Sciences > HD Industries. Land use. Labor > HD28 Management. Industrial Management Q Science > Q Science (General) T Technology > T Technology (General) |
| Faculty/Division: | Faculty of Industrial Sciences And Technology |
| Depositing User: | Mr Muhamad Firdaus Janih@Jaini |
| Date Deposited: | 27 Dec 2022 08:13 |
| Last Modified: | 27 Dec 2022 08:13 |
| URI: | http://umpir.ump.edu.my/id/eprint/33374 |
| Download Statistic: | View Download Statistics |
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