Augmentation of microbial fuel cell and photocatalytic polishing technique for the treatment of hazardous dimethyl phthalate containing wastewater

Sumaya, Sarmin and Tarek, Mostafa and Selvaraj Mohana, Roopan and Chin, Kui Cheng and Khan, Maksudur R. (2021) Augmentation of microbial fuel cell and photocatalytic polishing technique for the treatment of hazardous dimethyl phthalate containing wastewater. Journal of Hazardous Materials, 415 (125587). pp. 1-10. ISSN 0304-3894. (Published)

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Abstract

In the present paper, the potentiality of integrating microbial fuel cells (MFCs) with a photocatalytic reactor to maximize the wastewater treatment efficiency with concurrent power generation was explored. Dimethyl phthalate (DMP) and acetic acid (AA) were the employed substrate and the co-substrate, respectively, using Pseudomonas aeruginosa as a biocatalyst. MFCs operated by single substrate showed the maximum power generation of 0.75–3.84 W m−3 whereas an addition of AA as the co-substrate yielded 3–12 fold higher power generation. Pseudomonas aeruginosa produced phenazine-1-carboxylic acid in DMP-fed MFC as the metabolite whereas AA along with DMP yielded pyocyanin which reduced the charge transfer resistance. Chemical oxygen demand (COD) removal efficiency in the MFCs was circa 62% after 11 days of operation. Thereafter, it further increased albeit with a drastic reduction in power generation. Subsequently, the MFC anolyte was treated in a photocatalytic reactor under visible light irradiation and catalyzed by CuO-gC3N4. The performance of photocatalytic reactor was evaluated, with COD and total organic carbon (TOC) removal efficiency of 88% and 86% after 200 min of light irradiation. The present work suggests that the MFC can be integrated with photocatalysis as a sustainable wastewater treatment method with concurrent power generation.

Item Type: Article
Additional Information: Indexed by Scopus
Uncontrolled Keywords: Dimethyl phthalate; Microbial fuel cell; Photocatalytic technique; COD removal efficiency; High power generation
Subjects: T Technology > T Technology (General)
T Technology > TP Chemical technology
Faculty/Division: College of Engineering
Centre of Excellence: Centre of Excellence for Advanced Research in Fluid Flow
Institute of Postgraduate Studies
Depositing User: Pn. Hazlinda Abd Rahman
Date Deposited: 15 Nov 2022 07:10
Last Modified: 15 Nov 2022 07:10
URI: http://umpir.ump.edu.my/id/eprint/34365
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