Optimizing thermal properties and heat transfer in 3D biochar-embedded organic phase change materials for thermal energy storage

Yadav, Aman and Mahendran, Samykano and Pandey, A. K. and Kareri, Tareq and Kalidasan, B. (2024) Optimizing thermal properties and heat transfer in 3D biochar-embedded organic phase change materials for thermal energy storage. Materials Today Communications, 38 (108114). pp. 1-17. ISSN 2352-4928. (Published)

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Abstract

Enhancing the thermal properties and light-absorbing capabilities of phase change materials (PCMs) through the utilization of environmentally friendly, economically viable biochar materials is pivotal for optimizing solar energy capture and utilization. Herewith, initially, a green, three-dimensional, eco-friendly carbon nano inclusion is synthesized from Prosopis juliflora through vacuum oven carbonization at 130 °C, followed by size reduction via ball milling, promising high-impact contributions. Subsequently, green-synthesized nano-inclusions are dispersed in PEG-1000, creating advanced nano-enhanced phase change materials with improved thermo-physical properties using a two-step ultrasonication technique for enhanced thermal conductivity. This innovative study comprehensively explores the morphological behaviour, chemical stability, optical absorptivity, thermal properties, and reliability of the PEG-PJ composite. Remarkably, present research revealed that the composite achieved its highest thermal conductivity, an impressive 0.49 W/m⋅K, at 0.7 wt% of 3-D (PJ) biochar. Notably, the melting temperatures of the PEG-PJ composites consistently ranged from 40.1 °C to 40.5 °C. At the same time, their latent heat capacities displayed a notable increase, ranging from 145 J/g to 152.7 J/g, marking a substantial enhancement of 3.968% and 1.758%, respectively. Furthermore, to confirm the reliability and consistency of experimental findings, 500 thermal cycles were performed. Additionally, a numerical analysis study is conducted by utilizing 2-D energy modelling software to simulate the heat transfer rate owing to the improved thermal conductivity of the developed PEG-PJ composite PCM compared to PEG-1000. In conclusion, developed composites optimize solar storage, improve building thermal control, and enhance industrial heat exchangers for sustainable innovation in energy.

Item Type: Article
Additional Information: Indexed by Scopus
Uncontrolled Keywords: Eco-friendly; Green synthesis; Polyethylene glycol; Prosopis juliflora; Thermal stability
Subjects: Q Science > Q Science (General)
T Technology > TJ Mechanical engineering and machinery
Faculty/Division: Institute of Postgraduate Studies
Faculty of Mechanical and Automotive Engineering Technology
Depositing User: Mrs Norsaini Abdul Samat
Date Deposited: 20 May 2024 05:21
Last Modified: 20 May 2024 05:21
URI: http://umpir.ump.edu.my/id/eprint/41293
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