Recent advances in vitrimers: A detailed study on the synthesis, properties and applications of bio-vitrimers

Madduluri, Venkata Rao and Bendi, Anjaneyulu and Chinmay, , and Maniam, Gaanty Pragas and Rasidi, Roslan and Mohd Hasbi, Ab Rahim (2025) Recent advances in vitrimers: A detailed study on the synthesis, properties and applications of bio-vitrimers. Journal of Polymers and the Environment, 33 (1). pp. 301-322. ISSN 1566-2543. (Published)

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Abstract

Nowadays, thermoset polymers stand out as notable composites, but the surge in global thermoplastic production has raised concerns due to the non-recyclability of these composites, leading to an increase in landfill waste. In response to these challenges, researchers are investigating innovative approaches to enhance thermosetting materials, focusing on the modification of crosslinking agents responsible for forming a covalently bonded network. Vitrimers offer a promising solution by enabling re-processability while maintaining favourable thermo mechanical properties and solvent resistance. Although many current vitrimers use synthetic polymeric molecules from fossil-based sources, there is a growing interest in bio-based vitrimers. While still in early development, these bio-based alternatives leverage biomass for creating durable polymers, aligning with the goal of establishing a circular economy. This review has been designed to highlight the use of covalently modified networks to produce advanced synthetic and bio-based vitrimer composites with diverse applications, contributing to the development of sustainable materials for the next generation through the use of recyclable resources and renewable feedstocks in polymer network synthesis. This review also explores vitrimers, examining their unique characteristics and addressing current limitations hindering their widespread adoption as recyclable materials with superior performance.

Item Type: Article
Additional Information: Indexed by Scopus
Uncontrolled Keywords: Bio-Vitrimer; Covalent adaptable networks; Material science; Polymers; Sustainable development
Subjects: H Social Sciences > HD Industries. Land use. Labor
Q Science > Q Science (General)
T Technology > T Technology (General)
Faculty/Division: Faculty of Industrial Sciences And Technology
Centre for Advanced Intelligent Materials
Depositing User: Mr Muhamad Firdaus Janih@Jaini
Date Deposited: 20 Feb 2025 08:53
Last Modified: 20 Feb 2025 08:53
URI: http://umpir.ump.edu.my/id/eprint/43881
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