Tuning intrinsic lithiophilicity of copper foil to improve electrochemical performance of anode-free Li metal battery

Natarajan, Karthic and Wu, She–Huang and Wu, Yi–Shiuan and Chang, Jeng-Kuei and Jose, Rajan and Yang, Chunchen (2024) Tuning intrinsic lithiophilicity of copper foil to improve electrochemical performance of anode-free Li metal battery. Journal of Energy Storage, 84 (110880). pp. 1-10. ISSN 2352-152X. (Published)

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Abstract

Anode-free lithium metal batteries (AFLMBs) are currently attracting significant research attention due to their innovative lithium metal-free design. With a targeted N/P ratio of 0, AFLMBs rely exclusively on the cathode as the source of Li+ ions. Despite their potential to outperform traditional Li-ion batteries and emulate the performance of Li metal batteries, AFLMBs face a critical challenge stemming from the insufficient wettability of current collectors (CCs), such as copper (Cu) foil, by Li metal. This poor wettability results from a mismatch between the planes of CCs and Li, leading to uneven solid electrolyte interphase (SEI) growth and dead Li or dendritic lithium formation. To address this issue, we improve the Cu foil surface's affinity for lithium by subjecting it to a simple annealing process at 600 ◦C in a 5 % H2/Ar gas environment. This process effectively increases the Cu(200) planes, resulting in what we term single-faceted copper (SF-Cu). The lithiophilic SF-Cu demonstrates robust cycling performance, retaining 50.14 % of its initial capacity after 65 cycles with an impressive 98.95 % Li inventory retention rate (LIRR) in an AFLMB utilizing LiNi0.8Co0.1Mn0.1O2 (NCM811) as the cathode. Our as-prepared SF-Cu electrode emerges as a promising candidate for high-energy, anode-free Li metal battery applications.

Item Type:	Article
Additional Information:	Indexed by Scopus
Uncontrolled Keywords:	Anode-free Li metal batteries; Intrinsically lithiophilic Cu; Li deposition; Ni-rich cathode; Organo-fluoro-borate electrolyte; Surface reconstruction
Subjects:	T Technology > TK Electrical engineering. Electronics Nuclear engineering T Technology > TP Chemical technology
Faculty/Division:	Faculty of Industrial Sciences And Technology
Depositing User:	Mrs. Nurul Hamira Abd Razak
Date Deposited:	30 May 2025 07:56
Last Modified:	30 May 2025 07:56
URI:	http://umpir.ump.edu.my/id/eprint/44701
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