Rosmainiza, Ibrahimi Husaimi (2008) Development and characterization of sulfonated olyethersulfone membrane as a potential material for direct methanol fuel cell. Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang.
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Development and characterization of sulfonated polyethersulfone membrane as a potential material for direct methanol fuel cell.pdf - Accepted Version Download (775kB) | Preview |
Abstract
Sulfonated polyethersulfone membrane is one of the potential candidates to be use as an electrolyte for fuel cell application due to its high thermal resistance. With a high heat deflection temperature of 400°F (204°C), it can withstand continuous exposure to heat and still absorb tremendous impact without cracking or breaking. Sulfonated polyethersulfone membrane has been prepared by conducting sulfonation process with sulfuric acid as a sulfonating agent and then the polymer precipitated had been dissolved in N-Methyl-2-pyrrolidone. The functional groups of sulfonic acids have been successfully incorporated in the PES backbone and detected using FTIR at 1033cm -1 wavelength. Membranes with 35.7% degree of sulfonation possess water uptake at the room temperature of 13.1 wt% and the value of IEC is about 11.43 mmol/g. The water uptake of the sulfonated polyethersulfone membrane increased with temperature from 13.1 wt% up to 46 wt%. Meanwhile, the methanol uptake was increased with an increased in concentration from 14.9 wt% to 26.2 wt%. Membranes prepared from SPES showed lower decomposition temperature and have good properties to be applied as a membrane for DMFC.
| Item Type: | Undergraduates Project Papers |
|---|---|
| Additional Information: | Project paper (Bachelor of Chemical Engineering (Gas Technology) ) --- Universiti Malaysia Pahang - 2008, SV: PN. ROSMAWATI BT NAIM, NO CD: 2736 |
| Uncontrolled Keywords: | Membranes (Technology) |
| Subjects: | T Technology > TP Chemical technology |
| Faculty/Division: | Faculty of Chemical & Natural Resources Engineering |
| Depositing User: | Rosfadilla Mohamad Zainun |
| Date Deposited: | 13 Jul 2010 02:40 |
| Last Modified: | 14 Jul 2023 07:47 |
| URI: | http://umpir.ump.edu.my/id/eprint/787 |
| Download Statistic: | View Download Statistics |
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