Nor Shafiqah, Mohd Nasir and Nguyen, Trinh Duy and Jun, Lau N. and Mahadi, Bahari and Pham, T. T. Phuong and Bawadi, Abdullah and Vo, Dai-Viet N. (2018) Production of Syngas from Ethanol CO2 Reforming on La-doped Cu/Al 2O3: Impact of Promoter Loading. In: International Conference on Environment 2018 (ICENV2018) , 11-13 December 2018 , Batu Ferringhi Penang, Malaysia. pp. 1-10.. (Unpublished)
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Abstract
Incipient wetness impregnation (IWI) method was applied to prepared 10%Cu/Al 2 O 3 whereas M%La-doped 10%Cu/Al 2 O 3 (Mwt%= 1%, 2%, 3%, 4% and 5%) were synthesized by employing sequential IWI technique. The prepared catalysts were evaluated from ethanol CO 2 reforming (ECR) at 1023 K and stoichiometric feed ratio. Average crystallite size of CuO particle is reduced with La-promoter addition probably caused by lanthana dilution effect that prevent agglomeration from occur within CuO particles. H 2 reduction process produce complete CuO reduction and constant signal is appear beyond 525 K suggests that the catalysts were completely reduced beyond that temperature. 3%La catalyst identified as optimal promoter loading based on reactant conversions. C 2 H 5 OH and CO 2 conversions were achieved on 3%La loading is 87.6% and 55.1%, respectively. Carbon was identified on catalyst surface based on X-ray diffraction (XRD) and scanning electron microscopy (SEM).
| Item Type: | Conference or Workshop Item (Lecture) |
|---|---|
| Uncontrolled Keywords: | Ethanol dry reforming; La2O3; Syngas; Cu/Al2O3 catalyst; Hydrogen |
| Subjects: | T Technology > TP Chemical technology |
| Faculty/Division: | Faculty of Chemical & Natural Resources Engineering Institute of Postgraduate Studies |
| Depositing User: | Noorul Farina Arifin |
| Date Deposited: | 02 Jan 2019 03:56 |
| Last Modified: | 18 Oct 2019 03:00 |
| URI: | http://umpir.ump.edu.my/id/eprint/23569 |
| Download Statistic: | View Download Statistics |
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