Dewi, Rozanna and Sylvia, Novi and Zulnazri, Zulnazri and Riza, Medyan and Siregar, Januar Parlaungan and Cionita, Tezara (2025) Use calcium silicate filler to improve the properties of sago starch based degradable plastic. AIMS Environmental Science, 12 (1). pp. 1-15. ISSN 2372-0352. (Published)
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Abstract
The addition of fillers or additives to improve the mechanical properties of degradable plastics such as sago starch has gained the interest of researchers, scientists, and academicians. This research aims to investigate the addition of calcium silicate as an additive filler on the properties of a sago starch-based degradable plastic. The calcium silicate fillers used were 2, 4, 6, and 8% by weight starch, and the gelatinization process temperature used was 70, 80, and 90 °C. The properties of these plastics were analyzed in terms of their strength, chemical composition, thermal stability, water absorption, and degradation rate. The optimum mechanical characteristics included a tensile strength of 28.04 MPa, 32.55 MPa of elongation at the break, and 70.02% of Young’s modulus obtained with the addition of 8% calcium silicate and a gelatinization temperature of 90oC. Fourier Transform Infrared (FTIR) showed that there were O-H, C-H, and C=O groups that existed at wave numbers of 3795.91 cm-1, 2927.94 cm-1, and 1433.11–1616.35 cm-1; moreover, these groups are hydrophilic, which bind water, so they can be degraded by the microbial activity in the soil. Differential Scanning Calorimetry (DSC) showed that the degradable plastic had a thermogram peak at 271.38 °C; additionally an endothermic peak occurred at 309.30 °C. The maximum swelling value was 64.05% at 2% calcium silicate and a gelatinization temperature of 70oC. The addition of calcium silicate made the plastic more water-resistant. The degradation rate of the degradable plastic ranged from 12–15 days and conformed to the American Standard Testing and Materials (ASTM) D-20.96 (maximum 180 days of decomposition for degradable plastic).
| Item Type: | Article |
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| Additional Information: | Indexed by Scopus |
| Uncontrolled Keywords: | Calsium silicate; Degradable plastic; Filler; Sago starch |
| Subjects: | T Technology > T Technology (General) T Technology > TA Engineering (General). Civil engineering (General) T Technology > TJ Mechanical engineering and machinery T Technology > TL Motor vehicles. Aeronautics. Astronautics |
| Faculty/Division: | Faculty of Mechanical and Automotive Engineering Technology |
| Depositing User: | Mr Muhamad Firdaus Janih@Jaini |
| Date Deposited: | 19 Feb 2025 07:31 |
| Last Modified: | 19 Feb 2025 07:31 |
| URI: | http://umpir.ump.edu.my/id/eprint/43864 |
| Download Statistic: | View Download Statistics |
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